Hello and allow me to add my greetings and welcome.
I think it's hard to know what one person considers "small dents" versus the opinions of others. The first thing to do is go online or go to the lending library to get reference material that teaches basic body work. Even small dents can be frustrating to fix if you set off on wrong initial steps. Erling's three ingredients are definitely the key, particularly patience.
I can't say I'm expert in body work, but, on my motorcycle, I've done my own. As for powder coat, there is a variety of opinion, some expressed elsewhere in this forum. My own opinion is that it should be reserved for heavy steel parts that are not likely to get dented, like frames, engine mounts, cast-iron parts, et cetera. Tins can get dented and need repair, which is not simple with powder coat.
You should use a good plastic body filler with paste hardener. In the U.S., Bondo Ultimate would be a good choice. In the U.K., I'm not sure, I came across a couple of names but am hesitant to cite them for fear of mistake. You should buy a cheap dent hammer and a couple of dollies (meaning, heavy blocks of shaped steel that backup hammer hits; not meaning, assistants to soothe the labors of body work with further body work.)
As for where to put the filler, directly on bare metal roughed-up with 80-grit paper is the correct approach (reciting from my book). Take off enough old paint and filler so that the new filler and its feathered edges are all on bare metal. Inevitably, you will put new filler on top of new filler, for touching-up as you go with the new dent repair. This is not a problem, as long as the lower layers are roughed-up. Remember, you are going to want the minimum thickness filler. If the dent is accessible for pounding out, I'd say filler should not exceed 3mm, preferably less. I cheated on this for my tank, as I did not want to cut it in half to pound out a 35mm (diam.) x 9mm (deep) dent. In this case, I put the the filler on in layers. (There may be better approaches, but I am, after all, an amateur.) As for all the various following steps, this is where your reference material comes in.
I hope this helps in getting you started. Sorry, if I've been too wordy. It's Sunday morning and I am just having coffee and watching television while others sleep..
Richard L.